Carbohydrates
Carbohydrates
- Carbohydrates are the cell's quick energy molecules — and its building material.
- They come in three sizes, all built from sugar units.
- A tiny difference in one glucose shape decides everything that follows.
Three sizes of sugar
- A monomer is a single small unit; a polymer is many monomers joined into a long chain.
- A monosaccharide is one sugar unit — glucose, fructose.
- A disaccharide is two units joined — maltose, sucrose.
- A polysaccharide is many units joined into a polymer — starch, glycogen, cellulose.
- Glucose, fructose and maltose are reducing sugars; sucrose is non-reducing.
Which is a monosaccharide?
Glucose is a single sugar unit (monosaccharide); sucrose is a disaccharide; starch and glycogen are polysaccharides.
Joining and breaking: α and β glucose
- Glucose forms a six-carbon ring with two forms: in α-glucose the –OH on carbon 1 points down; in β-glucose it points up.
- Two sugars join by condensation: a glycosidic bond forms and one water molecule is removed.
- Hydrolysis is the reverse: adding water breaks the bond. (That's why the sucrose test needs acid + heat.)
When two monosaccharides join by a glycosidic bond:
A glycosidic bond forms by condensation — one water molecule is removed for each bond.
α-glucose and β-glucose differ in:
They are the same atoms — only the –OH on carbon 1 differs: down in α, up in β. This decides which polysaccharide forms.
Storage vs structure
- Starch (plants) and glycogen (animals) are made of α-glucose — coiled/branched, compact and insoluble, so they store energy without pulling in water by osmosis. Glycogen is the most branched, so it breaks down fastest.
- Cellulose is made of β-glucose: every other unit flips, giving long straight chains that bundle into strong microfibrils — the plant cell wall.
Cellulose is strong and structural because it is made of:
β-glucose chains are straight; many lie side by side and hydrogen-bond into strong microfibrils — the cell wall.
Why is glycogen a good energy store in animals?
Storage polysaccharides are compact and insoluble (no osmotic effect); glycogen's many branches give many ends for fast glucose release.
You've got it
- mono → di → polysaccharide; reducing sugars (glucose, maltose) vs non-reducing (sucrose)
- α-glucose –OH down → starch/glycogen (storage); β-glucose –OH up → cellulose (structure)
- condensation joins monomers (glycosidic bond, water removed); hydrolysis splits them (water added)
- storage polysaccharides are compact + insoluble; glycogen is most branched (fast release)